An associates degree doesn't count for much with employers in most markets but it you use it as the first two years of a bachelors degree there's no problem. The accreditation of the university you graduate from is what will matter.
As for UoP... I don't know if they have a real campus in Arizona, but their online program is not well regarded. A bachelors from them is probably better than just an associates from somebody else but (at least in the rest of the country) a degree from a local University (even with the first two years at a JC) will be more desirable.
I'd suggest the JC route with a transfer to a university. It will save you some money, let you make sure you really want this field before you commit too far, and probably give you the best education. Not to mention that an associates degree does count for something if your circumstances change and you have to start working more after less than four years.
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