If all you're talking about is TCP/IP connectivity, it shouldn't matter. The only time most sysadmins get antsy is if you start doing odd stuff on their network, like ARP poisoning and packet sniffing. If all you're doing is surfing the Web and the like, they'll probably never care what OS you're running.
They may have a policy about what OSes they allow on their network, but it's probably more of a technical support/ Help Desk issue. Don't expect to get much help from their IS/IT staff when running Linux. At the college I just finished from, the only thing the IT staff could do to "troubleshoot" our UNIX/Linux installs was to wipe it out and re-Ghost image it. Even then they had to come in and get one of the instructors to change the IP addresses on the "fixed" boxes!
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