Make sure you get Wine working with something simple before attempting to run the latest and greatest game! It should come with something like Notepad.exe, see if that works first. I also recommend reading Wine's documentation; it's very helpful, and I'd also try out other tools like winecfg, which is a configuration program for Wine.
And I heard there are still issues with some software, but it is worth buying if only because some of the knowledge accrued goes back into the wine project.
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