Well that depends as e'one say. You can use some other types of connections. However it depends on:
Service type and Port - To access web services you have to use an interface program which provides www services via port 80 and/or 80xx. If they allow the service through other ways you have to know those services and ports.
However Pc to Pc connection is quite easy with tools such as N-Central, logmein, RAdmin, Crossloop, Teamviewer. These tools will work only if the ports are allowed to be opened by perimeter firewalls.
If you have to connect to a enterprise network, you can use Terminal Services and Remote Desktop features. You can use commandline tools or tools with graphical interface.
Services that you can use:
For files transfers only, you can use ftp, tftp or sftp.
For voice and video transfers only, you can use RTP of the service if available
You can use Telnet to manage stuff (You have to securely configure it since its highly vulnerable. Its not recommended to use telnet).
You could use hyperterminal which is available in Windows.
Type of the Gateway - If gateways do not allow certain types of services, you will not be able to use them.
lasitha2005d
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