This isn't really a major problem. But you can go to where your itunes library is (just have alook round my docs) and you will find all the stuff there that you have downloaded of the itunes music store. Just delete it. Then resync your ipod and it should disapear. If that doesn't work you can go to the itunesipod summary page and select format or reset ipod and this will basically let you start again. Then make sure that you can't see the podcasts in your library and sync again.
Hope this helps
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Nearly a Posting Virtuoso
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since Oct 2005