Hi,
Network Sec occurs at all TCP/IP layers ie Physical layer security will deal with cable shielding, quantum cryptography, burglar proofing,CCTV, Proxy card and Biometric door access control systems, all in the name of protecting the physical network infrasructure.
The Data link and MAC layers will deal with security at the frame level, which means security aware switches bridges, and wireless security, such that you just dont come and plug your cable into the switch and start pinging all nearby computers.
At the Network layer, you are dealing with exiting the local switch-workstation-server,network to another network having its own switches, workstations and servers. Here, you have routers and you are actually dealing with how each router vendor incorporates security into his products.
At the transport layer, you are dealing with application programming using sockets and ports so your program can talk to another program out there on another network, you have security libraries built into programming language compilers so your program is end to end secure.
At the application layer, you will find the usual network applications like Email,WWW,Multimedia, Database servers like DB2, File servers, and System managers like SMS.
In all these layers, the following security algorithms are in common use, so you need to assess the network layer you are working in and then find the appropriate algorithm. Standards set up by ISO,ITU-T,IEEE and IETF bodies for security in each layer will usually be of vital help ie IPSec for Network layer security,SSL for application and transport layer security, WEP for wireless security though not secure anymore than the RC4 algorithm it was based on, GSM security for mobile phones though also not secure than the A5/1 algorithm it was based on and other standards too are available.
There are two basic algorithms in Network security ie Symmetric key algorithms and Public key algorithms.
In the former you have DES,Triple DES,Twofish,Blowfish,RC5,IDEA, etc
In the latter RSA is mainly used.
Network security is a wide study, but i hope you find this useful.