It is faster, and more expensive. DDR2 has lower latencies, but DDR3's speed makes up for this.
Since most intel CPUs have locked multipliers, you have to do some serious overclocking to get your FSB up to somewhere near the RAM speed. So with DDR3 the RAM is really outpacing the rest of the system (a large divider ratio).
Some people report a performance difference, but I'm sceptical. The only reason to go DDR3 in my opinion is if you're doing Nehalem, which would mean money is no object.
If you've got any questions about the 750i or any other SLI related queries I recommend asking the people at SLIzone.
I have to point out that Intel chipsets (non-SLI) do overclock better than NVidia ones. The P45, for example, will overclock higher but doesn't do SLI.
PS: oh yeah, get the 750i FTW edition if you're going 750i. It's got solid state capacitors for longer life.
http://www.evga.com/articles/401.asp