Firewire was designed to transfer large quantities of data at a sustained high speed, so it is possible that you will see a performance gain by using it. Unless you really need to save some minutes; however, I don't see it giving you sizable performance gains.
If you want to try it out, go to any store that has computer equipment and pick up a cheap PCI Firewire or Firewire/USB2.0 combo card. They run anywhere from $10-30, so it shouldn't be too expensive. Even if you end up sticking with the USB2.0 connection, you will still have extra ports to use.