I said that you need libtk-devel and libtcl-devel if you want to build with tkinter. If the libraries don't show in the list, you must check that your rpm sources configuration is good: open the mandriva control center (it should be System->Administration->Configure your computer, sorry I have a french localisation, so I don't know the exact name of the menu entries in english). In the Control center, you go to software management and select configure the sources (before doing this, close your package manager). On my system I have the sources HTTP Main, HTTP Main updates HTTP Main32, HTTP Main32 updates HTTP contrib, HTTP contrib updates, HTTP non-free and HTTP non-free updates.
I can't build python 3 with tkinter here because I have a 64 bits processor and I read that it won't work...
You must run the software installer when your internet connection is working

. In principle you don"t need the cdrom.
By the way, I'm sure that you never COMPILED python on windows. When mandriva will have a rpm for python 3, it will be as easy to install as it is on windows.