Configuring in OpenLDAP 2.1 and later - Since 2.1, the client libraries will verify server certificates. This change requires clients to add the TLS_CACERT (or, alternately, the TLS_CACERTDIR) option to their system-wide ldap.conf(5) file. Without this setting, the LDAP clients will fail to make any TLS/SSL connections to any servers.
See the Using TLS chapter of the OpenLDAP Software Admin Guide for more information
http://www.openldap.org/faq/index.cgi?_highlightWords=ssl&file=185
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