Assuming that you are using the vb.net webbrowser, read on.
If this is for a login to a website, the link should have an Id. For example, using the following html page to navigate to,
<html><head><title>Untitled Page</title></head>
<body>
<a href="http://www.daniweb.com" id="myLink">to be clicked link</a>
</body>
</html> and using the following code toget the proper link by id,
Private Sub WebBrowser1_DocumentCompleted(ByVal sender As System.Object, ByVal e As System.Windows.Forms.WebBrowserDocumentCompletedEventArgs) Handles WebBrowser1.DocumentCompleted
For Each link As HtmlElement In WebBrowser1.Document.Links
If link.Id = "myLink" Then
WebBrowser1.Navigate(link.GetAttribute("href"))
Exit For
End If
Next
End Sub my webbrowser navigates to http://www.daniweb.com .