Black magic perhaps?
You can't convert a binary executable file into an XML file. Of all the things XML may be, a programming/compilable language it is not. Perhaps you could get a script interprettor that worked with XML, but a translator from an EXE would be another matter entirely.
You might be able to convert a database into XML though. I imagine there are tools to do that, and it could even be done manually. I wouldn't advise it personally, because a straight 'translated' XML version of a small database (just tables without relationships) would be much larger than the original database, and cross-hierachy relationships (i.e. relationships beyond the obvious structure of a document) aren't easy to express using XML.
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