To send an email is fairly easy. First you need to import the System.Net.Mail namespace to get access to everything you need. Then you create an instance of an SmtpClient (which you provide with the details regarding the email account that will be sending the email) and a MailMessage instance which holds the subject, message, attachments, etc. Then send it.
You'll find plenty of good tutorials online. Here is one to start you off:
http://www.dreamincode.net/forums/topic/57355-sending-e-mail-messages-using-c%23/
hericles
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