This maybe the simplest example I could ever think of.. Say, your above xml file is called test.xml, then you can easily parse the email XX and the name: XX from it by using these few lines of php codes.
<?php
## type in your xml file location
$xml ='test.xml';
## remove @ to debug
$xml = @simplexml_load_file($xml);
foreach($xml as $items)
{
echo "Name: ".$items->value[2]." Email: ".$items->value[4]."<br/>";
}
?>
We can also assign them into variables as you wish, as shown in my example below..