You can see other entries by using mysql_data_seek(): http://www.php.net/manual/en/function.mysql-data-seek.php
When using while() with mysql_fetch_array() there will be a move of the internal row pointer for the query result, so it moves from one key to another, automatically:
<?php
$result = mysql_query("SELECT * FROM post_categories");
$row = mysql_fetch_array($result);
echo $row['Name'];
print_r($row);
mysql_data_seek($result, 1);
$row = mysql_fetch_array($result);
print_r($row);
mysql_data_seek($result, 2);
$row = mysql_fetch_array($result);
print_r($row);
?> bye :)
note: using mysql_fetch_array() you will end up with an array with both numerical and field name keys, if you use mysql_fetch_assoc() you will get just the table field names.