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I don't think a listview control is what you want. I think it would look more like a normal question screen if you had an array of radio buttons. On your form, place one radio button, then copy and paste it, VB will ask if you want to create a control array, answer yes. then keep pasting until you have the desired number of radio buttons.

When you retrieve a record from the database populate the captions of the radio buttons.

Place some code under the click event of the control array to check if the user has selected the correct answer