I am new to writing scripts. I should have probably started years ago but as I'm having a go can someone tell me if by learning HTML and CSS which I know is good for computers is this the best script to learn for mobile apps aswell?

Depending on how you build your mobile app. you can use html5 and javascript library like jquery mobile, you can built a native app. Native apps like iOS or andrioid have their own language. Mobile frameworks are becoming popular now, it makes it real easy to build an app. Sencha Touch is a mobile framework

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