Under the .NET tab, I don't have anything that begins with "Microsoft Office" listed.
Under the COM tab, there are numerous "Microsoft Office..." options, but none contain "word.dll". Closest I seem to be able to find is "Microsoft Word 12.0 library" under COM.
Try opening a Word document and keep it open, or open another VS session and create a project of type office document...Then, go back in look in the References->Add dialog of your project in question and I think you will see it. If not, you can use the Browse tab and locate the Word.DLL in your Program Files or wherever you have it installed.
You may also want to visit these links:
http://www.c-sharpcorner.com/...SpellCheckCC.aspx
http://www.codeproject.com/KB/office/SpellCheckUsingWord.aspx
EDIT: I know there was a discussion on using a richtextbox with spellchecker in this forum recently, but I can never seem to get the forum search to work for me...