print " through echo statement

try using single qoute for the double quotes and double quoutes for the single quotes. Otherwise, yo can escape it. Another alternative is to use heredoc for a longer string., but for your situation something like this will do..
<?php
echo '"';
echo "' '";
?>

You need to escape the double quote with a backslash:

<?php
echo " \" ";
?>

thanks for your response.
i will keep that in mindand use it in future.