It's hard to help you without the full traceback of the error but here's my two cents:
You're parsing the file contents incorrectly. What you should be doing is splitting each line at the tab character to get time stamp, port number, then the remaining string of floats. At this point you can sum the floats together and get a single float for your data list.
Here's how I would parse the data you provided:
>>> data_stor = []
>>> for line in file_hol:
... data = line.split('\t')
... if len(data) == 3:
... tstamp = data[0].strip()
... port = data[1].strip()
... valu = sum([float(ea) for ea in data[2].strip().split()])
... data_stor.append([tstamp, port, valu])
...
>>> max(data_stor, key=lambda x:x[2])
['501', '6', 7.7770000000000001]
>>>
This returns that port 6 at timestamp 501 has the highest sum of numbers.