Do you mean you want to retrieve the name of a column in a DataTable?
If yes, DataTable.Columns[ColumnIndex].ColumnName return the name of the column specified by 'ColumnIndex'.
For example, to retrieve the name of the 4th column from the DataTable object 'dtEmp',
String colName = dtBooks.Columns[3].ColumnName ;
Note that the column index starts with 0.