Many of the software development forums have a sticky thread featured at the top for recommended resources on getting started with or improving one's knowledge of that language. VB.NET currently has no such resource listing.
I personally do not work with VB.NET, but if those who do would like to post recommended resources here in this thread I can compile such a sticky thread for the forum. It can be very helpful for both the newbies seeking resources and veterans who are tired of making the same recommendations for the seventy-fourth time. ;)
The thread itself will most likely be a work in progress that I will edit as necessary to keep it cleaned up and on-topic.